The tensile strength and number-average molecular weight for two poly(methyl methacrylate) materials are as follows: Tensile Strength (MPa) Number-Average Molecular Weight (g/mol) 36 30,000 150 50,000 Estimate the tensile strength at a number-average molecular weight of 46,000 g/mol. MPa

Answer :

Answer:

The required tensile strength is 175.13 MPa.

Explanation:

Given that,

Tensile strength(MPa)                Number Average Molecular weight(g/mol)

       36                                                               30,000

      150                                                               50,000

First we need to find out  [tex]TS_\infty[/tex]tensile strength at infinity molecular weight.

The formula of tensile strength

[tex]TS=TS_\infty-\frac{A}{ M_n}[/tex]

TS is tensile strength,[tex]TS_\infty[/tex] at infinity molecular weight, [tex]M_n[/tex] is molecular weight and A is constant.

Now substituting [tex]TS=36[/tex] and [tex]M_n=30,000[/tex]

[tex]36=TS_\infty-\frac{A}{30,000}[/tex]

[tex]\Rightarrow TS_\infty=36+\frac{A}{30,000}[/tex]  ........(1)

Now substituting [tex]TS=150[/tex] and [tex]M_n=50,000[/tex]

[tex]150=TS_\infty-\frac{A}{50,000}[/tex]

[tex]\Rightarrow TS_\infty=150+\frac{A}{50,000}[/tex] ......(2)

Subtract (1) from (2)

[tex]TS_\infty-TS_\infty=150+\frac{A}{50,000}-36-\frac{A}{30,000}[/tex]

[tex]\Rightarrow150+\frac{A}{50,000}-36-\frac{A}{30,000}=0[/tex]

[tex]\Rightarrow \frac{A}{30,000}-\frac{A}{50,000}=150-36[/tex]

[tex]\Rightarrow \frac{5A-3A}{1,50,000}=114[/tex]

[tex]\Rightarrow \frac{2A}{1,50,000}=114[/tex]

[tex]\Rightarrow A=\frac{1,50,000 \times114}{2}[/tex]

[tex]\Rightarrow A=8,550,000[/tex]

Putting the value of A in equation (1)

[tex]TS_\infty=36+\frac{8,550,000}{30,000}[/tex]

        =361 MPa

Now to find the tensile strength at a number average molecular weight of 46,000 g/mol , Putting the value [tex]TS_\infty[/tex], TS and A

[tex]\therefore TS=361-\frac{8,550,000}{ 46,000}[/tex]

         = 175.13 MPa

The required tensile strength is 175.13 MPa.

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