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the equilibrium constant at 250C for the equation PCl5 PCl3 is kp 4.5 x 10^3 bar calculate value of grxn at 250C in which direction is reaction spontaneous when pcl3 cl2 standard conditions

Answer :

znk

Answer:

-36.6 kJ·mol⁻¹  

Explanation:

1. Calculate ΔG

[tex]\text{The relationship between $\Delta G^{\circ}$ and K is}\\\Delta G^{\circ} = -RT \ln K[/tex]

T = (250 + 273.15) K = 523.15 K

[tex]\begin{array}{rcl}\Delta G & = & -8.314 \text{ J}\cdot\text{K}^{-1} \text{mol}^{-1} \times \text{523.15 K} \ln (4.5 \times 10^{3}) \\& = & -4349\text{ J}\cdot \text{mol}^{-1} \times 8.412\\& = & \text{-36 590 J}\cdot \text{mol}^{-1}\\& = & \textbf{-36.6 kJ}\cdot \text{mol}^{-1}\\\end{array}[/tex]

2. Direction of spontaneity

ΔG is negative, so the reaction is spontaneous in the forward direction.

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